The appropriate time to consider a DOE is when you're short on experimental time/money (which is always) or overwhelmed by a lot of factors (i.e., you don't know which are important or how they interact).
You say you need to decide on a thesis on the subject of “Design of Experiments”
This, hopefully, means you are studying for your MS or PhD
The coursework you are doing should have given you some exposure to “Design of Experiments” of different types and possibly in different sciences (Chemistry, Biology, Physics, etc..)
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